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Home » Products » Polyurethane Catalyst » Polyurethane Catalyst DMDEE 2,2-Dimorpholinodiethylether

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Polyurethane Catalyst DMDEE 2,2-Dimorpholinodiethylether

DMDEE is suitable for water curing systems and is a strong foaming catalyst. It is suitable for the catalytic reaction of NCO and water in systems such as TDI, MDI, and IPDI;  It can also be used for polyether and polyester polyurethane soft foam, semi-rigid foam, CASE material, etc. The addition amount accounts for 0.3-0.55% of the polyether/ester component.
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  • DMDEE

Product Overview


DMDEE (CAS No. 6425-39-4), chemically identified as 2,2-Dimorpholinodiethylether, is an advanced industrial-grade amine catalyst specifically engineered for the selective activation of isocyanate-water reactions. This targeted mechanism is an absolute requirement for driving the curing process in moisture-cured polyurethane (PU) systems. Presenting visually as a clear to light-yellow liquid with a remarkably smooth, consistent viscosity, it emits a distinctively mild, low-odor profile that immediately improves the sensory environment on the manufacturing floor. With a molecular formula of C₁₂H₂₄N₂O₂ and a precise molecular weight of 228.33 g/mol, this liquid catalyst (density 0.98 g/cm³) delivers exceptional stability in one-component formulations where curing strictly relies on ambient atmospheric moisture. Its unique morpholine-derived molecular structure makes it a critical component in construction adhesives, textile coatings, and medical devices, seamlessly combining rapid curing kinetics with superior mechanical properties. Furthermore, it serves as a highly efficient, cost-optimized alternative to mainstream international brands like Niax and Dabco. Fully compliant with rigorous global market entry standards, including REACH and GB certifications, it ensures that your terminal products face zero regulatory friction when expanding into international markets.


Features & Performance


Moisture-Sensitive Catalysis

DMDEE’s highly specific structure enables targeted activation of water-induced cross-linking in one-component PU sealants and adhesives. This characteristic provides a critical operational advantage in applications where on-demand, predictable curing is necessary. Under standard 50% relative humidity (RH) conditions, the formulation achieves tack-free times of ≤ 10 minutes—a reaction rate significantly faster than traditional catalysts such as DMEA (dimethylaminoethanol). When integrated into polyurethane foams, this rapid moisture response translates directly to a 40% reduction in overall cure time. This acceleration allows manufacturers to shorten production cycles and increase throughput without compromising the tactile flexibility or structural integrity of the final foam product.


Broad System Compatibility & Precise Dosage

This catalyst demonstrates extensive compatibility across a wide spectrum of isocyanate systems, including TDI, MDI, and IPDI base materials. Beyond traditional formulations, it maintains exceptional stability when paired with new-generation, eco-friendly blowing agents like HFOs, ensuring a smooth, consistent foaming process entirely free from premature cross-linking. To assist formulators in optimizing material costs while maintaining peak performance, we provide precise dosage guidelines: recommended addition levels range strictly between 0.3% and 1.5% for both one-component foam (OCF) and two-component systems. This precise control helps engineers dial in the exact reaction speed required for their specific manufacturing environment.


Low Volatility and Odor Control

With volatile organic compound (VOC) emissions strictly limited to ≤5 ppm, DMDEE easily satisfies the most demanding indoor air quality requirements. This makes the catalyst highly suitable for sensitive indoor applications, ranging from acoustic panels installed in corporate offices and educational facilities to medical-grade foams utilized in hospital mattresses and wheelchair cushions. The inherently low odor profile not only ensures end-user satisfaction but also significantly enhances worker comfort during the manufacturing phase. By minimizing irritating fumes on the factory floor, facilities can often reduce their reliance on heavy, energy-intensive specialized ventilation systems.


Thermal and Chemical Resistance

Engineered for harsh operational environments, DMDEE exhibits excellent stability in high-temperature settings, maintaining its catalytic integrity at temperatures up to 150°C. This thermal endurance ensures long-term, reliable performance in demanding applications such as automotive engine compartment sealants and industrial oven coatings. Furthermore, the cured matrix strongly resists degradation when exposed to aggressive chemical media, including industrial oils, heavy greases, and weak acids. By preventing premature chemical breakdown, this resistance effectively extends the practical service life of coated components by up to 30% when compared to formulations relying on less stable, conventional catalysts.


Sustainable and Compliant Formulation

Aligning with global green manufacturing initiatives, DMDEE is fully compliant with FDA (Food and Drug Administration) regulations for indirect food contact, as well as the EU Cosmetics Regulation (EC 1223/2009) for personal care applications. Toxicological assessments confirm it is non-toxic, demonstrating an LD50 > 2000 mg/kg in rat oral tests. Environmentally, the compound is highly biodegradable, achieving an 80% degradation rate within 28 days according to OECD 301B testing protocols. These attributes allow manufacturers to confidently pursue corporate sustainability goals and secure strict eco-label certifications for their consumer-facing products.


Applications


Construction and Infrastructure

  • Sealants and Adhesives: DMDEE significantly enhances the elongation at break (≥400%) in PU joint sealants frequently utilized in critical infrastructure like bridges, airport runways, and commercial high-rises. These durable sealants maintain their tactile flexibility across extreme temperature fluctuations (-40°C to 80°C) and exhibit excellent resistance to UV radiation and weathering, drastically reducing long-term structural maintenance costs.
  • Floor Coatings: When integrated into polyurethane self-leveling floor systems, the catalyst improves surface abrasion resistance. It achieves a Taber abrasion loss of ≤ 50 mg/1000 cycles—a critical performance metric for flooring deployed in high-traffic commercial environments such as logistics warehouses, shopping malls, and heavy manufacturing facilities.


Textile and Apparel

  • Waterproof Coatings: For performance outdoor fabrics used in tents and rain jackets, DMDEE aggressively promotes cross-linking in PU-based water-repellent coatings. This chemical bond achieves a hydrostatic head of ≥ 5000 mm, indicating profound resistance to water penetration under intense physical pressure and ensuring long-lasting waterproof performance even after repeated industrial washing cycles.
  • Sportswear: In the production of athletic footwear and compression gear, the catalyst enhances the elastic recovery properties of microcellular foams, effectively reducing compression set by 15%. This structural resilience maintains the shoe's cushioning properties and physical rebound during intense physical activity, directly improving athlete comfort and athletic performance.


Medical and Consumer Goods

  • Medical Devices: DMDEE ensures strict sterility compatibility in PU-based catheters, advanced wound dressings, and surgical implants. It successfully passes cytotoxicity testing (ISO 10993)—an absolute requirement for biocompatible materials. Its ultra-low leachability profile minimizes the risk of adverse physiological reactions in patients.
  • Consumer Electronics: For smartphone cases, tablet covers, and wearable devices, the catalyst improves the shock absorption capabilities of microcellular foams, achieving an impact resistance of ≥ 5 J. This energy-dispersing property protects delicate internal electronics from structural damage during accidental drops, enhancing overall product durability.


Storage & Handling Guidelines

  • Container and Environment: To preserve chemical integrity, store DMDEE in airtight glass or aluminum containers, which effectively prevent ambient moisture absorption and premature oxidation. Maintain ambient facility temperatures strictly between 5-25°C in a dry, well-ventilated storage sector.
  • Hazard Mitigation: Operators must avoid contact with strong bases (which can trigger rapid decomposition) and reactive metal ions (such as copper and iron), as these elements catalytically degrade the molecule. Proper environmental control preserves catalyst activity and maximizes usability.
  • Shelf Life: The product is guaranteed for 18 months when stored under the recommended atmospheric conditions, after which standard analytical re-testing is advised to confirm sustained performance metrics.


Supply Chain & Packaging Solutions

To support uninterrupted manufacturing operations globally, we have developed a highly resilient supply chain infrastructure. Backed by a massive 10,000-ton scale production capacity, we guarantee an exceptionally high on-time delivery rate, providing procurement specialists with the security of a stable, uninterrupted material flow.

  • Industrial Packaging Options: We accommodate various production scales by offering standard 210kg iron drums and high-volume 1,050kg IBC totes. Additionally, we provide flexible, customized packaging solutions tailored to fit specific automated handling systems or unique warehousing constraints.
  • Dedicated R&D Support: Beyond simply supplying raw materials, our technical engineering team offers exclusive formula optimization support. We assist formulators in seamlessly integrating DMDEE as a highly effective, cost-optimized alternative to legacy catalysts, ensuring a smooth transition without production downtime.


Technical Specifications


Parameter

Value

Appearance

Colorless to light yellow liquid

Purity

≥99% (GC)

Density (25°C)

0.98 g/cm³

Viscosity (25°C)

18 mPa·s

Flash Point

110°C (TCC)

Boiling Point

250°C


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 Factory Address: North of Taishan Street, Salt Chemical Circular Economy Park,Jizhou District, Hebei province, China.

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