Views: 0 Author: Site Editor Publish Time: 2026-03-04 Origin: Site
Rigid polyester polyols are widely used in closed-cell spray polyurethane foam (SPF) systems for insulation, roofing, tanks, and cold storage applications. Compared with polyether systems, polyester-based spray foams offer higher compressive strength and better fire performance, making them suitable for demanding insulation projects.
| Property | Typical Range |
|---|---|
| Hydroxyl Value (mgKOH/g) | 300–450 |
| Functionality | 2.8–3.5 |
| Viscosity (25°C) | 3,000–12,000 mPa·s |
| Acid Value | ≤ 2.0 mgKOH/g |
| Water Content | ≤ 0.1% |
| Density (25°C) | 1.10–1.25 g/cm³ |
Higher OH value → higher crosslink density → better compressive strength.
✔ Fast reactivity (short cream & gel time)
✔ Fine closed-cell structure
✔ High compressive strength (200–350 kPa typical)
✔ Good adhesion to metal & concrete
✔ Better dimensional stability
✔ Improved fire behavior vs polyether systems
Rigid polyester polyols are typically synthesized from:
Aromatic acids (e.g., phthalic anhydride)
Glycols (DEG, EG)
Recycled PET (cost-effective rigid grades)
Small amount of crosslinkers for functionality control
Aromatic content enhances fire performance and rigidity.
Polyol Side (Component B):
Rigid polyester polyol: 100 pbw
Blowing agent (cyclopentane or HFO): 8–15 pbw
Water: 1.5–3.0 pbw
Silicone surfactant: 1.5–2.5 pbw
Amine catalyst: 1.0–2.0 pbw
Tin catalyst (e.g., Stannous octoate): 0.2–0.5 pbw
Flame retardant (if required): 10–20 pbw
Isocyanate Side (Component A):
Polymeric MDI
ISO index: 110–130 (PU spray foam)
Material temperature: 20–25°C
Spray pressure: 100–150 bar (high-pressure machine)
Substrate moisture must be controlled
Good mixing ratio control is critical
| Property | Polyester | Polyether |
|---|---|---|
| Compressive Strength | Higher | Medium |
| Fire Resistance | Better | Moderate |
| Dimensional Stability | Better | Good |
| Hydrolysis Resistance | Lower | Higher |
If you are developing spray insulation foam, I can help you with:
Optimized formulation for tropical climate (important in Vietnam)
Low-density roofing spray system
High-density structural spray foam
Pentane vs HFO blowing comparison
TDS specification sheet template for customers
