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Home » News » XINFA Poyurethane Manufacture Supply Rigid Foam Polyester Polyol For Spraying Foam

XINFA Poyurethane Manufacture Supply Rigid Foam Polyester Polyol For Spraying Foam

Views: 0     Author: Site Editor     Publish Time: 2026-03-04      Origin: Site

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Rigid polyester polyols are widely used in closed-cell spray polyurethane foam (SPF) systems for insulation, roofing, tanks, and cold storage applications. Compared with polyether systems, polyester-based spray foams offer higher compressive strength and better fire performance, making them suitable for demanding insulation projects.


1️⃣ Typical Technical Specifications

PropertyTypical Range
Hydroxyl Value (mgKOH/g)300–450
Functionality2.8–3.5
Viscosity (25°C)3,000–12,000 mPa·s
Acid Value≤ 2.0 mgKOH/g
Water Content≤ 0.1%
Density (25°C)1.10–1.25 g/cm³

Higher OH value → higher crosslink density → better compressive strength.


2️⃣ Performance Characteristics in Spray Foam

✔ Fast reactivity (short cream & gel time)
✔ Fine closed-cell structure
✔ High compressive strength (200–350 kPa typical)
✔ Good adhesion to metal & concrete
✔ Better dimensional stability
✔ Improved fire behavior vs polyether systems


3️⃣ Raw Materials Commonly Used

Rigid polyester polyols are typically synthesized from:

  • Aromatic acids (e.g., phthalic anhydride)

  • Glycols (DEG, EG)

  • Recycled PET (cost-effective rigid grades)

  • Small amount of crosslinkers for functionality control

Aromatic content enhances fire performance and rigidity.


4️⃣ Typical Spray Foam Formulation (Example)

Polyol Side (Component B):

  • Rigid polyester polyol: 100 pbw

  • Blowing agent (cyclopentane or HFO): 8–15 pbw

  • Water: 1.5–3.0 pbw

  • Silicone surfactant: 1.5–2.5 pbw

  • Amine catalyst: 1.0–2.0 pbw

  • Tin catalyst (e.g., Stannous octoate): 0.2–0.5 pbw

  • Flame retardant (if required): 10–20 pbw

Isocyanate Side (Component A):

  • Polymeric MDI

  • ISO index: 110–130 (PU spray foam)


5️⃣ Key Processing Parameters

  • Material temperature: 20–25°C

  • Spray pressure: 100–150 bar (high-pressure machine)

  • Substrate moisture must be controlled

  • Good mixing ratio control is critical


6️⃣ Advantages vs Polyether Polyol in Spray Foam

PropertyPolyesterPolyether
Compressive StrengthHigherMedium
Fire ResistanceBetterModerate
Dimensional StabilityBetterGood
Hydrolysis ResistanceLowerHigher

If you are developing spray insulation foam, I can help you with:

  • Optimized formulation for tropical climate (important in Vietnam)

  • Low-density roofing spray system

  • High-density structural spray foam

  • Pentane vs HFO blowing comparison

  • TDS specification sheet template for customers


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