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Rigid Foam Polyester Polyol XF-390 For Pentane Foaming

Pentane-foaming Polyester Polyol refers to polyester polyols specifically designed for polyurethane (PU) rigid foam systems where pentane (n-pentane, iso-pentane, or cyclopentane) is used as the physical blowing agent instead of HCFCs/HFCs.
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  • XF-390;XF-360;XF-2402N;


1. What it is

A pentane-compatible polyester polyol is:

  • A low-viscosity, high-reactivity polyester polyol

  • Formulated to dissolve and stabilize pentane

  • Used mainly in rigid polyurethane (PUR) and PIR foams

Pentane is flammable, so the polyol must ensure:

  • Good pentane solubility

  • Stable foam rise

  • Fine and uniform cell structure


2. Key characteristics

PropertyTypical Requirement
Hydroxyl value200–300 mg KOH/g
Functionality2.2–3.0
Viscosity (25 °C)Low to medium (for pentane compatibility)
Acid value≤ 1.5 mg KOH/g
Pentane solubilityHigh
Aromatic contentMedium–high (better insulation & strength)

3. Why polyester polyol for pentane foaming?

Compared with polyether polyols, polyester polyols offer:

✔ Better pentane solubility
✔ Higher closed-cell content
✔ Improved dimensional stability
✔ Lower thermal conductivity (λ-value)
✔ Better compressive strength

This makes them ideal for insulation foams.


4. Typical applications

Pentane-foaming polyester polyols are widely used in:

  • Refrigerator & freezer insulation

  • Continuous panel / sandwich panel foams

  • Insulated pipes

  • Cold-storage panels

  • Rigid PIR boards


5. Common pentane types used

  • n-Pentane – lower cost, slightly higher λ-value

  • iso-Pentane – better flowability

  • Cyclopentane – best insulation performance, most common in appliances

Polyester polyols are often tailored to the specific pentane type.


6. Formulation considerations

When using pentane foaming polyester polyol:

  • Use special surfactants (silicone stabilizers for pentane)

  • Adjust catalyst balance (pentane slows reaction)

  • Ensure explosion-proof equipment

  • Control processing temperature (pentane volatility)


7. Typical product examples (industry)

  • Aromatic polyester polyols for cyclopentane systems

  • Low-viscosity polyester polyols for continuous panel foaming

  • PIR-grade polyester polyols for high-temperature resistance


8. Parameters

Product ModelHydroxyl value   (mgKOH/g)Acid Value   (mgKOH/g)Moisture                    (%)Viscosity                (CPS 25℃)
XF-360370±20≤2.0≤0.151500±500
XF-390400±20≤2.0≤0.152000±500
XF-2402N240±10≤1.5≤0.18000±1500


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