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Manufacture Provide High Efficiency Polyester Polyol For Controlled-release Fertilizers

Polyester polyols are key components in creating controlled-release fertilizer (CRF) coatings, forming durable, biodegradable polymer layers (often polyurethane or aliphatic polyester) around nutrient granules, controlling release rates through thickness and composition, offering benefits like reduced nutrient runoff, lower application frequency, and improved crop efficiency by slowly diffusing nutrients as water penetrates the semi-permeable membrane. They are synthesized from diols and dibasic acids, offering tunable properties (molecular weight, functionality) and often combined with waxes, bio-based materials (like castor oil), or fillers (like silica) for enhanced performance and sustainability.
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  • XF-270; XF-B-1;

Product Introduction: 

Polyester polyols are key functional materials used in controlled-release fertilizer (CRF) coatings because they allow precise tuning of nutrient release, mechanical strength, and biodegradability.

This specialized polyester polyol enables precise regulation of nutrient release kinetics in controlled-release fertilizers, ensuring sustained and efficient nutrient uptake by crops throughout their growth cycle. Additionally, customized coloration is achievable via the incorporation of tailored color powders or pigments.


1. Why Polyester Polyols Are Used in Controlled-release Fertilizers

Polyester polyols are mainly used as reactive components in polyurethane (PU) coatings applied to fertilizer granules (e.g., urea, NPK).

They help achieve:

  • Controlled nutrient release rate

  • Water resistance with controlled permeability

  • Good coating strength & adhesion

  • Potential biodegradability (depending on structure)


2. Role in Polyurethane-Coated Fertilizers

Polyester polyols react with isocyanates (MDI, TDI, PDI) to form polyurethane membranes.

Function of the PU coating:

  • Water penetrates slowly through the coating

  • Nutrients dissolve inside the granule

  • Nutrients diffuse out gradually

The polyester polyol structure directly controls diffusion speed.


3. Key Polyester Polyol Properties 

(1) Molecular Weight

  • Low MW (500–1000) → faster nutrient release

  • Medium MW (1000–3000) → balanced release

  • High MW (>3000) → slow, long-term release

(2) Functionality (OH number)

  • Higher OH number → higher crosslink density → slower release

  • Typical OH value: 50–200 mg KOH/g

(3) Backbone Composition

Common acids:

  • Adipic acid → flexible, good permeability control

  • Succinic / Sebacic acid → improved biodegradability

  • Phthalic / Isophthalic acid → increased rigidity, slower release

Common glycols:

  • Ethylene glycol (EG)

  • Diethylene glycol (DEG)

  • 1,4-Butanediol (BDO)

  • Neopentyl glycol (NPG)


4. Release Control Mechanisms

Polyester polyols influence:

  • Hydrophilicity / hydrophobicity

  • Coating density

  • Micro-porosity

  • Swelling behavior in soil moisture

By adjusting formulation, CRFs can be designed for:

  • 30–45 days

  • 60–90 days

  • 120–180 days nutrient release


5. Biodegradable Polyester Polyols (Growing Trend)

To meet environmental regulations, manufacturers increasingly use:

  • Aliphatic polyester polyols

  • Bio-based acids (succinic, sebacic)

  • Bio-based glycols

These allow:

  • Gradual coating degradation after nutrient release

  • Reduced microplastic accumulation in soil


6. Specifications 

SpecificationXF-270XF-B-1
AppearanceLight yellow to brownish yellow transparent liquidLight yellow to brownish yellow transparent liquid
Hydroxyl value,mgKOH/g260±10300±30
Acid value,mgKOH/g3±0.2≤3.0
Moisture content,%≤0.1≤0.15
Viscosity,mPa·s(25℃)3000±5003000±500
UsesThis product is a biodegradable resin, suitable for fertilizer coating.This product is a biodegradable resin, suitable for fertilizer coating.
Packaging, storage and transportationPacked in iron drums, net weight 200kg per drum.Packed in iron drums, net weight 200kg per drum.

7. Applications

This polyester polyol serves as a critical raw material in the manufacturing of diverse controlled-release fertilizer formulations, including urea-based controlled-release fertilizers, potash-based controlled-release fertilizers, and compound controlled-release fertilizers.



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